" I also know that he moved his master socket... or at least, he re-wired his internals to a configuration which he understood meant moving it."
That sounds rather concerning, if only because it's more than slightly ambiguous. You can't move a master socket just redoing your internal wiring. Moving the master socket would mean altering the BT wiring where it comes into the property by either rerouting it, or possibly extending it using a junction box. I hope that hasn't been done, especially as if there is a line fault and an engineer visits, there may be a big bill.
However, if what this actually means is that some extension wiring has been connected to the master socket faceplate and what your friend regards as the master socket (and where the router is connected) is actually an extension, then that's OK of course. If it's done that way, and uses cheap non-twisted pair extension cable (and most is like that) then it will be sub-optimal. It will be particularly vulnerable to noise if what's called the "ringwire" is connected on the extensions (that's connection 3 on the faceplate). It's essentially redundant on modern phones, and definitely unnecessary where microfilters are used. A quick fix for DSL issues is often just to disconnect the ringwire on the extensions at the master socket end.
However, this is still not great. It is much better to filter all the extension wiring at the master socket with a maximum of one unfiltered extension where you might want to locate a router/modem. That unfiltered extension should ideally use high quality twisted pair cabling (like cat6 cabling). Then all the microfilters can be thrown away save possibly one at the extension socket where the router/modem is to be located. (A neater way to do this is to install an extension faceplate with both RJ11 DSL and a standard phone sockets and feed both filtered and unfiltered outputs down a single cat6 cable using different pairs).
There are several ways of doing this, but if he has the right sort of master socket, then a VDSL IS is a good way to go. It has two connections for an unfiltered pair and the standard extension wires are all fully filtered (which means, of course, that VDSL will not work on any of those).
A useful check to see if it makes any difference is to attach the router direct to the incoming line with all the extensions disconnected. That's easily achieved with modern masters by removing the faceplate and plugging the router/modem into the test socket underneath. Then compare stats (especially noise margin, sync speed and attainable rates) with the standard setup. If they are substantially better (that is higher), then redoing the internal wiring is certainly worth considering.
Note that there's an earlier ADSL iplate, but it only filters the ring wire and doesn't fully filter extensions. There's video guidance on this site for that earlier iplate, but it's not applicable to this, which is the VDSL iplate. (But it will also work on ADSL of course).
http://www.run-it-direct.co.uk/btvdslfaceplate.html



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