Yes.
What's available to you depends on where you are located. The ThinkBroadband
UK broadband map is a good place to look for information.
A number of companies provide fibre-to-the-home in specific areas: e.g. Cityfibre, Gigaclear, Hyperoptic, and many smaller companies with limited footprints.
Leased lines are available in many areas of the country from networks other than Openreach, although these are relatively expensive business services.
Virgin Media is using FTTP (RFoG) for its newer deployments.
Have you got a more specific requirement?