Short answer: no. Voice frequencies (up to 4kHz) are not used for data, apart from dial-up modems
Longer answer: FTTC and ADSL do use non-overlapping frequency bands. There are FTTC profiles available which cover both bands, which would make FTTC work both faster and over longer distances, but can't be used until all ADSL is gone.
Turning off ADSL isn't going to happen, because there are LLU operators like Talktalk and Sky who have their own DSLAMs in the exchange, and are providing DSL services.
By the time all of those have gone, then pretty much the whole country will be on FTTP anyway. At that point we won't be talking about optimising FTTC: we'll be talking about removing the FTTC cabinets entirely.