Does the CCTV DVR IPv6 address start with fe80 or fdxx or a global 2xxx?
All interfaces can self-assign an IPv6 address (by design) but that doesn't mean it is globally route-able.
More importantly, does the CCTV DVR IPv6 configuration show a default gateway? Irrespective of the type of IPv6 address being assigned, if a device doesn't have a route to / from the rest of the Internet, it is not really on the Internet, even if is pingable from the router itself (or any other device on the same link-local network).
Devices only obtain information about the default gateway if they are either configured with one statically or (more usually) receive it from a router advertisement (RA).
If a device has previously received a RA which has then gone away, the IPv6 address becomes tentative/provisional before it is removed completely, because the design makes allowances for intermittent faults which may be recovered within a configurable time interval.
Also, you mention the DVR has been configured with a false IPv4 address for its gateway. This is a common misconception but the address should be removed or left blank as otherwise the DVR will constantly be trying to contact this fake address (for any destinations not on the local subnet).
For a standalone network where you don't want something to talk to other networks it is both valid and desirable to have no gateway assigned and UIs which force you to enter a gateway address are at fault.
Likewise real DHCP servers can also be configured to assign IP addresses with or without DNS settings and with or without gateway address (it is not all or nothing), so some consumer routers which don't provide this option are also lacking.
I only mention this because you could ultimately solve both questions by placing the DVR (or all the CCTV devices) behind a real router and even provide desired configuration (both IPv4 and / or IPv6) by DHCP, if the Sky Router is limiting your options.
prlzx on iDNET: VDSL / 21CN at ~40Mbps / 10Mbps
with IP4/6 (no v6? - not true Internet)
Edited by prlzx (Wed 16-Jan-19 21:06:31)