I found residential ISPs to be unreliable
Describe "unreliable"? What network and technology was the connection being delivered over?
It sounds like you might be thinking about several different things:
* Same technology (e.g. GPON FTTP) but "residential" versus "business" provider. The "business" provider may give you a better SLA - e.g. they may take Enhanced Care from Openreach - and/or better support. There are quite a few providers who offer the Enhanced Care option (e.g. Aquiss, AAISP, Cerberus). They'll likely use the same network for business and resi customers.
* Different transit providers (ISPs) and different access networks. You mention Community Fibre and Hyperoptic, but if you have Openreach FTTP available then it gives you a much wider choice of transit providers.
The quality of network operations varies from provider to provider, which will affect how many outages there are in their core network and how quickly they're resolved.
* Different access technology, e.g. dedicated leased line versus FTTP. This will give you a full symmetric 1G/1G (or more). The business providers will happily sell you this regardless of the building type, but whether you want to pay ten times or more as much is for you to decide. You may have Excess Construction Charges, and you'll likely end up with a three year contract that auto-renews for 1 year periods if you don't cancel it 90 days before the renewal date. And has already been pointed out, installation into an MDU may be problematic.
* Different ASNs: I'm not aware of any providers splitting their business and resi customers into different ASNs, and TBH they'd likely share the same transit ASN anyway: it makes no sense for them to have two sets of peerings, and I don't think this would have any of the advantages you think it does. All serious UK ISPs have tons of peering at the main exchange points like LINX and LONAP, and/or private peering, because it's financially in their interests to do so. If you want a "business only" ASN then you're best going for a provider who sells only business connections. But there's no guarantee of better connectivity.
Whether you count Community Fibre and Hyperoptic as "serious ISPs" is for you to decide.
Aside: if connectivity to AWS and Microsoft are critical, you can also buy direct connections to them. But normally you'd do that from a data centre.