Try this programme "intrusion detection system SAX2"
http://www.ids-sax2.com/
You can filter by application, osi layer, port, network interface and protocol as well as items accessing the lan, wan or both. You can have lots of graphs, save logs and export to excel plus you can view the the contents of individual tcp and udp packets and datagrams.
OR .......
open up a command prompt with admin rights (right click - run as administrator) and type the following
netstat -a -b
then press enter and wait a moment or two for the list to appear. you will be able to see which application has net access, it's current status, any protocols, ip addresses, port numbers etc.