If they tried to place a FTTC order and your Digital Region is still active then yes that will fail.
You need to tell your DR ISP that you want to leave and cease that service, which frees the line up so PlusNet can place the FTTC order. This is where you get the possibility of a gap where you have no broadband at all for a week or two.
For no gap, get MAC migrate from DR to ADSL2+ and then place an order for FTTC after the 1 month minimum is up on the ADSL2+ service.