It looks too consistent for a bolier or heating related issue ... same time every night and not in the mornings. Although, if you have continual hot-water and only have the heating one for those few hours in the evening, then it might the valve controls ...
If your Sky & TV tests don't show anything, try putting the heating ON and see if that makes changes - or this eveing, have periods of CH & HW off, CH on, HW on and both off.
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taurus excreta cerebrum vincit