IS there a link on how to order and start the ball rolling?
Firstly you need to choose a service provider who sells FTTPoD. There are only two national ones that I know of: Cerberus and FluidOne. There are some which cover only parts of the country - e.g. Spectrum, Syscomm - and there are some companies which are resellers of the other ones - e.g. Amvia resells Cerberus.
You apply for a free desktop quote from them, which takes a week or two. Then if you decide to place an order, you pay £250+VAT; over the next 2-3 months the survey takes place and the final price is generated. This bears little relation to the desktop quote (fortunately, in most cases it's
lower). Then you have 30 days to decide whether you're happy to proceed and pay the balance - or to pull out and forfeit the £250.
How to apply for voucher scheme if available?
Or is someone has any links to forms that need filling in.
Tell your service provider, and they apply on your behalf. You can read the T&Cs
here. Vouchers are only available for businesses, or for homes applying in conjunction with a business.
You mention a group of applications. If all interested parties are on the same
distribution point (usually same manhole cover or pole) then one person taking FTTPoD will make native FTTP available for the others to order - this is the cheapest way to do it, but you need to sort out between you the sharing of costs. Those taking native FTTP will also benefit from a wider range of service providers and various deals / cashback offers. The FTTPoD purchaser can switch to these after their initial 12 month contract period of course.
It's also possible to have linked FTTPoD orders, which would be appropriate if a few nearby DPs need activating. However these are more complex, more expensive (each person is taking a business ISP service for at least 12 months), and riskier (if one person cancels, the order collapses and the monies paid are lost)