..... Since I've gone through about 6 PSU's in this PC.....
There were a few boards of about this vintage that exhibited strange behaviours including PSU strains and related BSOD's etc. Memory is something of a stranger these days but something tells me that they may well have been Gigabyte boards.
The problem was eventually found to be within the PCB manufacturing process whereby the boards were wrongly cut and exposed PCB tracks were unwittingly brought out to the edge of the board at the backplane end.
The cure was simple - Remove the board, stick a narrow strip of insulation tape across the back of the board so that the edge was no longer exposed to the case or addin cards metalwork.
If it isn't that, watch out for the board mounts as I've often seen a metal standoff and screw where plastic or even nothing at all should have been used. Sometimes, insulating washers are left off and even a slightly bent case chassis can cause problems.
Often, these "short hazards" won't be noticeable until the temparature rises enough to cause expansion and bang!