As far as University goes, I'm not sure that it matters that much. I suspect that most software used there for these subjects is UNIX/Linux based rather than Windows or OS X.
It's (marginally) easier to install Linux on a PC; on the other hand, OS X being a UNIX-based OS it would be easier to port software to it. But you pay quite a premium for the Apple name.
Overall, I'd go for a Windows based PC on the assumption that if your daughter studies Maths/Engineering at that level she'll probably be geeky enough to install Linux and any software she needs. You'll get much better value for your outlay.
I'd disagree with the suggestion to get a tablet; the software just won't be there for them (and, although easier to hide, they are easier to steal). Porting software to a tablet is something of a nightmare (and requires a normal computer anyway).



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