Hi,
My thoughts...
1) Go for 5.5GHz to 5.7GHz rather than 5.8GHz as then there is no need for the Ofcom licence
2) 5km is easy with line of sight and aliging units is also easy at that distance (just use a pair of binoculars to spot the other end, then point in that direction)
3) For ease of use, I would tend to suggest a couple of Ubiquiti units like these:
http://www.wifi-stock.co.uk/details/ubiquiti_nanosta... Just set one up as AP and the other as Station/Client and make sure you select correct frequency band.
cheers
Peter