This is becoming quite common. Install, update and run Malwarebytes' Antimalware in Safe mode and fix anything that it finds. Please post the log file here if anything is found.
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Daughter's machine was doing a similar thing.... or so I thought.
I ended up tracking it down a site that "http://www.photodropperz.com" that she had "logged in" to with her MSN ID as a "friend" sent her a link to a photo.
The site no longer exists but there are load of other domain names that pop up and some are quite convincing. In the Ts&Cs on the site it blatently says that by supplying your username / password authorises them to send messages on your behalf. Scumbags.
They were sending out further harvesting sites and porn - not great as she's just 11 years old!
I got her to change her password and within about 20 mins she got a "recovery password" email than she didn't request. These emails from MSN continued for about 2-3 weeks (several a day).
So I'm guessing you've had a virus that's either grabbed the details and is not sending out messages on her behalf , or you've signed into one of these sites witout realising it.