Good! The 2nd pair to the old upstairs office must be deaded somewhere in the house.
So the line split outside house does not come into play and all your current line wiring must come off the downstairs NTE5 master.
The upstairs socket should not be an NTE5 master and may be affecting things by the presence of its duplicate master capacitor in the circuit.
1999: Freeserve 48K Dial-Up => 2005: Wanadoo 1 Meg BB => 2007: Orange 2 Meg BB => 2008: Orange 8 Meg LLU => 2010: Orange 16 Meg LLU => 2011: Orange 20 Meg WBC